CO在有K沉积的W(100)面上吸附的角分辨紫外光电子能谱

在不同K覆盖度的W(100)面上吸附CO的Hel紫外光电子能谱研究表明:α和β态的CO由于K的影响,吸附状态发生改变,与CO分子态(α态)有关的5σ/1π分子轨道能级随K覆盖度的增加,结合能位置从8.6eV移到9.3eV,反映K出现后,衬底对α-CO分子反施的增强。在与CO分解态(β态)有关的谱峰位置上(结合能为5.5eV)出现两个离散的谱峰,一个在6.0eV左右,另一个在5.2eV左右。其中结合能在5.2eV左右的谱峰强度随K的覆盖度增加而增大,它的能量位置与O在K覆盖的W(100)面上吸附时的能级位置 关键词：

ARUPS INVESTIGATION OF CO COADSORPTION WITH K ON W(100) SURFACE

Hel ultraviolet photoemission studies of CO coadsorption with different K coverages on W (100) surface show that the 1π/5σ level of α-CO shifts from 8.6eV to 9.3eV relative to the Fermi level while the K coverages increase, this indicates the increase of electron backdonation into 2π^* of α-CO. Two independent peaks are found around 5.5 eV (Characteristic of β-Co), one is at 5.2eV, another is at 6.0eV. The peak at 5.2eV grows with increasing K coverages, its energy position is the same as that of O coadsorption with K on W(100) surface, this suggests that K forms bond to O of β-CO.