Inhibition of mild steel corrosion in HCl solution using chitosan |
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Authors: | Saviour A. Umoren Mauro J. Banera Teodoro Alonso-Garcia Claudio A. Gervasi Maria V. Mirífico |
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Affiliation: | 1. Departamento de Química, Facultad de Ciencias Exactas, Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA, CCT La Plata-CONICET), Universidad Nacional de La Plata, Casilla de Correo 16, Sucursal 4, 1900, La Plata, Argentina 2. Department of Chemistry, Faculty of Science, University of Uyo, Uyo, Nigeria 3. Biosurfaces Unit, CIC biomaGUNE, Paseo Miramón 182 C, 20009, San Sebastián, Gipuzkoa, Spain 4. Laboratorio de Ingeniería de Corrosión y Tecnología Electroquímica (LICTE), Facultad de Ingeniería, UNLP, 1 y 47, 1900, La Plata, Argentina
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Abstract: | The efficiency of chitosan (a naturally occurring polymer) as a corrosion inhibitor for mild steel in 0.1 M HCl was investigated by gravimetric, potentiodynamic polarization, electrochemical impedance spectroscopy measurements, scanning electron microscopy, and UV–visible analysis. The polymer was found to inhibit corrosion even at a very low concentration. Inhibition efficiency increases with a rise in temperature up to 96 % at 60 °C and then drops to 93 % at 70 °C, while it slightly increases with an increase in chitosan concentration. Polarization curves indicate that chitosan functions as a mixed inhibitor, affecting both cathodic and anodic partial reactions. Impedance results indicate that chitosan was adsorbed on the metal/solution interface. Adsorption of chitosan at the mild steel surface is found to be in agreement with Langmuir adsorption isotherm model. Chemical adsorption is the proposed mechanism for corrosion inhibition considering the trend of protection efficiency with temperature. Calculated kinetic and thermodynamic parameters corroborate the proposed mechanism. |
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