Kinetics and mechanism of the decomposition of Cs2Pt[CH3]2Cl4 in aqueous solution with concurrent formation of C2H6, C2H4, and C2H5Cl |
| |
| Authors: | V V Zamashchikov V G Popov |
| |
| Institution: | (1) L. M. Litvinenko Institute of Physico-organic and Coal Chemistry, Academy of Sciences of Ukraine, Donetsk |
| |
| Abstract: | Reductive elimination of ethane from Cs2Pt(CH3)2Cl4 in aqueous chloride solutions at 368 K is accompanied by C-H bond scission. A mechanism is proposed for the reaction which includes the intermediate formation of an ethylhydrideplatinum(IV) and an ethylplatinum(II) complex.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 29, No. 2, pp. 154–158, March–April, 1993. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
