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Intermolecular proton transfer in solid phase: a rare example of crystal-to-crystal transformation from hydroxo- to oxo-bridged iron(III) molecule-based magnet
Authors:Armentano Donatella  De Munno Giovanni  Mastropietro Teresa F  Julve Miguel  Lloret Francesc
Institution:Dipartimento di Chimica, Università della Calabria, via P. Bucci, 87036 Rende, Cosenza, Italy.
Abstract:Intermolecular proton transfer in solid phase from the hydroxo bridge to a water molecule occurs in a new mu-hydroxo iron(III) compound of formula {EtNH3Fe2(ox)2Cl2(mu-OH)].2H2O}n leading to a still crystalline compound in which the mu-oxo bridge replaces the mu-hydroxo one. Both three-dimensional compounds exhibit magnetic ordering at Tc ca. 70 K due to a spin canting.
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