Heptanuclear clusters of osmium: crystal structure of [Os7(CO)20P(OMe)3] |
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| Affiliation: | 1. College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, PR China;2. Testing Center, Fuzhou University, Fuzhou, 350116, PR China;3. Key Laboratory of Eco-materials Advanced Technology, Fuzhou University, Fujian Province, PR China;1. Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Department of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, China;2. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;3. Institut de Chimie de Strasbourg, CNRS-UMR7177, Université de Strasbourg, 67070 Strasbourg Cedex, France |
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| Abstract: | The structure of [Os7(CO)20P(OMe)3] has been determined by an X-ray diffraction study. The metal-atom skeleton consists of a capped octahedron, in which the capping Os-atom bears the P(OMe)3 ligand and two terminal COs, while the other six Os-atoms bear three terminal COs each. |
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