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On the explosive properties of 1H-benzotriazole and 1H-1,2,3-triazole
Authors:Marcus Malow  Steffen Neuenfeld
Institution:a Bundesanstalt für Materialforschung und -prüfung (BAM), Division II.2 ‘Reactive Substances and Systems’, Unter den Eichen 87, 12205 Berlin, Germany
b Merck KGaA, Central Process Development, ZV/T-SL, 64271 Darmstadt, Germany
Abstract:For 1H-benzotriazole, no explosive properties are observable, but the relative high exothermic decomposition energy of 1590 J/g should be kept in mind. Nevertheless, an endothermic melting barrier at 100 °C ensures safe handling at lower temperatures. For 1H-1,2,3-triazole, the exothermic decomposition energy is as high as 2600 J/g, but explosive properties are also not detectable. Therefore, both reagents are hazardous with regard to the exothermic decomposition potential and can be handled safely with precautions.
Keywords:1H-Benzotriazole  1H-1  2  3-Triazole  Explosive properties  DSC
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