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Homochiral tripodal imidazolium receptors: structural and anion-receptor studies
Authors:Nameer Alhashimy  Dermot J Brougham  Joshua Howarth  Alan Farrell  Brid Quilty  Kieran Nolan
Institution:a School of Chemical Sciences, Dublin City University, Glasnevin, Dublin 9, Ireland
b National Institute for Cellular Biotechnology, Dublin City University, Glasnevin Dublin 9, Ireland
c School of Biotechnology, Dublin City University, Glasnevin, Dublin 9, Ireland
d National Centre for Sensor Research, Dublin City University, Glasnevin, Dublin 9, Ireland
Abstract:Two homochiral tripodal receptors were characterised by X-ray crystallography, the first examples for this class of imidazolium receptor. These receptors were also screened for anion recognition. Both receptors demonstrated selectivity towards chloride and bromide with binding constants as high as 16,000.
Keywords:Tripodal imidazolium receptors  Homochiral  Anion recognition  X-ray  Candida albicans
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