A selective and convenient ruthenium mediated method for the synthesis of mixed acetals and orthoesters |
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| Authors: | Stanis?aw Krompiec Robert Penczek Jan Grzegorz Ma?ecki |
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| Institution: | a Institute of Chemistry, Faculty of Mathematics, Physics and Chemistry, University of Silesia ul. Szkolna 9, 40-007 Katowice, Poland
b Faculty of Chemistry, Silesian University of Technology, ul. B. Krzywoustego 4, 44-100 Gliwice, Poland |
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| Abstract: | Addition of alcohols and phenols to O-allyl compounds (allyl ethers and acrolein acetals), catalyzed by RuCl2(PPh3)3], was examined. Intramolecular addition of an OH group, leading to the formation of cyclic acetals and orthoesters, was also investigated. As a result, a new, selective and convenient method for the synthesis of symmetrical and unsymmetrical (mixed) acetals and orthoesters was developed. |
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| Keywords: | O-Allyl compounds Addition Ruthenium complexes Mixed acetals Orthoesters |
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