Phenyl versus alkyl migration in the fragmentation of alkoxychlorocarbenes |
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| Authors: | Robert A. Moss Xiaolin Fu |
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| Affiliation: | Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, NJ 08903, United States |
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| Abstract: | Phenyl versus methyl (alkyl) group migration is assessed in the fragmentations of neophyloxychlorocarbene, 2,2-diphenylpropyloxychlorocarbene, and 1-phenylcyclopropylmethoxychlorocarbene. Rate constants and activation parameters of the fragmentations are also reported. |
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