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An investigation of the complexation properties of cyclobis(paraquat-p-phenylene) in water |
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| Authors: | Marc Bria Alan Cooper Shanika Gunatilaka Hewage Gouher Rabani |
| Affiliation: | a CCM-RMN Lille 1, Université des Sciences et Technologies de Lille, Villeneuve d’Ascq 59655, France b WestCHEM, Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow G12 8QQ, UK c Laboratoire de Chimie Organique et Macromoléculaire, Université des Sciences et Technologies de Lille, Villeneuve d’Ascq 59655, France |
| Abstract: | This article reports the characterization of pseudorotaxanes fabricated from cyclobis(paraquat-p-phenylene) 1, and 1,4-dialkyloxyphenyl derivative 2 or 1,5-dialkyloxynaphthalene derivative 3 in water. Addition of competing guest 3 to 1.2 or the electrochemical reduction of the cyclophane of 1.3 results in a dethreading of the original pseudorotaxane architecture. |
| Keywords: | Supramolecular chemistry Pseudorotaxanes Tuneable |
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