| Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction |
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| 引用本文： | ZhiQuanZHAO LiZengPENG YuLinLI. Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction[J]. 中国化学快报, 2005, 16(3): 290-292 |
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| 作者姓名： | ZhiQuanZHAO LiZengPENG YuLinLI |
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| 作者单位： | [1]LunanPharmaceuticalCo.,Ltd.,Linyi,Shandong276003 [2]NationalLaboratoryofAppliedOrganicChemistry,InstituteofOrganicChemistry,LanzhouUniversity,Lanzhou730000 |
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| 摘 要： | The phenomenon of migration of the silyl groups from α-oxygen to β-oxygen in sodium aldol reaction was observed for the first time in this paper.
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| 关 键 词： | 甲硅烷基迁移 醛醇缩合反应 α-甲硅烷氧基酮 三烷基甲硅烷基保护基团 |
Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction |
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| Zhi Quan ZHAO,Li Zeng PENG,Yu Lin LI Lunan Pharmaceutical Co.,Ltd.,Linyi,Shandong National Laboratory of Applied Organic Chemistry. Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction[J]. Chinese Chemical Letters, 2005, 16(3): 290-292 |
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| Authors: | Zhi Quan ZHAO Li Zeng PENG Yu Lin LI Lunan Pharmaceutical Co. Ltd. Linyi Shandong National Laboratory of Applied Organic Chemistry |
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| Affiliation: | Zhi Quan ZHAO1,Li Zeng PENG1*,Yu Lin LI2* 1Lunan Pharmaceutical Co.,Ltd.,Linyi,Shandong 276003 2National Laboratory of Applied Organic Chemistry,Institute of Organic Chemistry,Lanzhou University,Lanzhou 730000 |
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