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球壳粒子悬浮系模型化研究——内部相参数对介电谱影响的数值模拟
引用本文:赵孔双,疋田巧,李子杰,雷建平,裘乐乐. 球壳粒子悬浮系模型化研究——内部相参数对介电谱影响的数值模拟[J]. 高等学校化学学报, 2003, 24(5): 850-853
作者姓名:赵孔双  疋田巧  李子杰  雷建平  裘乐乐
作者单位:1. 北京师范大学化学系,北京,100875
2. 华南师范大学化学系,广州,510631
基金项目:国家自然科学基金(批准号:20273010,29873015),教育部高等学校骨干教师资助计划资助
摘    要:在Hanai理论基础上对球壳粒子悬浮系的介电模型进行了模拟研究,通过用C++的复数类对理论公式的程序化,建立了介电谱的介电参数与体系内部相参数的关系.所得的解析解可方便地模拟介电弛豫谱依不同相参数的变化曲线,计算并分析了内部参数对介电谱的模式以及介电参数的影响因素.

关 键 词:介电弛豫谱  球型介电模型  Hanai理论
文章编号:0251-0790(2003)05-0850-04
收稿时间:2002-09-02

Model Study on the Suspension in Spherical Shell-structure——Numerical Simulation for the Influence of Inner Parameters on the Dielectric Spectroscopy
ZHAO Kong-Shuang,HIKIDA Takumi,LI Zi-Jie,LEI Jian-Ping,QIU Le-Lc. Model Study on the Suspension in Spherical Shell-structure——Numerical Simulation for the Influence of Inner Parameters on the Dielectric Spectroscopy[J]. Chemical Research In Chinese Universities, 2003, 24(5): 850-853
Authors:ZHAO Kong-Shuang  HIKIDA Takumi  LI Zi-Jie  LEI Jian-Ping  QIU Le-Lc
Affiliation:1. Department of Chemistry, Beijing Normal University, Beijing 100875, China;
2. Department of Chemistry, South China Normal University, Guangzhou 510631, China
Abstract:A simulation study of suspension in spherical shell-structure was made on the basis of Hanai theory. An improved and intelligentized program for solving the tedious equations from Hanai theory has been written with C language and complex class, and been applied to the numerical calculations of permittivities and conductivities at different frequencies from 10 to 107 Hz. The dependence of dielectric spec-troscopy on the inner parameters of the system was obtained by an example actualized in a microcapsule suspension. The results show that the patterns of the spectroscopy can be reflected qualitatively by the electric and structural parameters of the constituted phases of the system.
Keywords:Dielectric relaxation spectroscopy  Spherical dielectric model  Hanai theory
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