An iron-57 Mössbauer spectroscopic study of titania-supported iron- and iron-iridium catalysts |
| |
Authors: | Frank J. Berry Simon Jobson |
| |
Affiliation: | (1) School of Chemistry, University of Birmingham, Edgbaston, B15 2TT Birmingham, UK |
| |
Abstract: | 57Fe Mössbauer spectroscopy shows that titania-supported iron is reduced by treatment in hydrogen at significantly lower temperatures than corresponding silica- and alumina-supported catalysts. The metallic iron formed under hydrogen at 600°C is partially converted to carbide by treatment in carbon monoxide and hydrogen. In contrast to its alumina- and silica-supported counterparts, the remainder of the titania-supported iron is unchanged by this gaseous mixture. The57Fe Mössbauer spectra and EXAFS show that iron and iridium in the titania-supported iron-iridium catalysts are reduced in hydrogen at even lower temperatures and, after treatment at 600°C, are predominantly present as the iron-iridium alloy. The treatment of these reduced catalysts in carbon monoxide and hydrogen is shown by Mössbauer spectroscopy and EXAFS to induce the segregation of iron from the iron-iridium alloy and its conversion to iron oxide. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|