| Synthesis and Stuctural Characterization of the Complex [Et4N]2[Ni（C2S |
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| 引用本文： | 盛天录,吴新涛,等.Synthesis and Stuctural Characterization of the Complex [Et4N]2[Ni（C2S[J].结构化学,1999,18(1):22-26. |
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| 作者姓名： | 盛天录 吴新涛 等 |
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| 作者单位： | State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002 |
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| 摘 要： | The heteroleptic dmit complex Et4N]2Ni2(C2S4)(C3S5)2] has been prepared by the reaction of NiCl2.H2O with Na2dmit, NaSC2H4OH in the MeOH solution. The compound has been characterized by X-ray diffraction study, IR and UV-Vis spectroscopy. Crystallographic data : space group: P21/n, a=11.843(2), b=11.079(1), c = 15.404(1)(), β=110.33(1)°, V = 1895.1()3, Z=2, Dc=1.62 g/cm3, μ=17.6 cm-1, F(000)=956, R=0.052, Rw=0.061. In the structure of the title complex, the tto (tto=tetrathioxalato) ligand in bridging form is chelated to two nickel atoms and dmit (dmit=1,3-dithiole-2-thione-4,5-dithiolate) ligands coordinated to nickel atoms.
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| 关 键 词： | 合成 结构 二元配合物 镍配合物 1 3－二硫杂环戊二烯－2－硫酮－4 5－二硫醇盐 |
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