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1H NMR Study of the Photoisomerization of Cinamylidene-2-Methyl-5-Chloro aniline
Authors:Layla M N Saleem  Ahmed S Authman
Institution:1. Department of Chemistry, College of Education , University of Mosul , Mosul, Iraq;2. Medical Department , Council of Technical Institute , Erbil, Iraq
Abstract:Abstract

Cinamylidene-2-methyl-5-chloro-aniline undergoes isomerization from the trans form to the cis form under irradiation with u.v. light at room temperature. The isomerization was studied in three solvents and the % cis was found to be in the following order: in DMSO 〉 CDCl3 〉 CCl4. The rate of the process of isomerization was found to be a first order one.
Keywords:Molecular structure and spectroscopy  Symmetric cyclotriphosphazatrienes
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