Synthesis of enantiomerically enriched secondary and tertiary phenylthio- and phenoxy-aldols |
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| Authors: | Angela M Bernard Pier Paolo Piras Francesco Secci Marco Spiga |
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| Institution: | Dipartimento di Scienze Chimiche, Università di Cagliari, Complesso Universitario di Monserrato, S.S. 554, Bivio per Sestu, I-09042 Monserrato (Cagliari), Italy |
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| Abstract: | α-Phenoxy- and phenylthio-ketones have been explored as donors and acceptors in organocatalytic aldol reactions. Our studies have revealed effective methodologies for accessing structurally varied and enantiomerically enriched secondary and tertiary phenylthio- and phenoxy-aldols, expanding the scope and potential synthetic utility of organocatalytic direct aldol reactions. |
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| Keywords: | Organocatalyst Asymmetric reaction Aldol reaction Proline |
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