Reaction of tetrachloroethylene with methanol under pressure |
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| Authors: | L. K. Salamandra Yu. B. Vol'kenshtein M. A. Besprozvannyi L. P. Gudovich G. I. Nikishin |
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| Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions A method was developed for the preparation of trichloroallyl alcohol from methanol and tetrachloroethylene in a titanium apparatus under a pressure of 100–120 atm in the presence of CC14 (335°), CH3COC2H5 (365°) or (CH3)3COOC (CH3)3 (185°), in a yield of 35–55% when based on starting TCE and 85–90% when based on reacted TCE, with a reactor output of up to 1000 g/h liter.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2868–2870, December, 1974. |
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