Reversible structural isomerisation in rare thioether complexes of cobalt(II)--effects of ligand architecture |
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| Authors: | Evans John Levason William Manning Joanna M Reid Gillian Tsoureas Nikolaos Webster Michael |
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| Institution: | School of Chemistry, University of Southampton, Highfield, Southampton, UKSO17 1BJ. |
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| Abstract: | Rare examples of (high spin) Co(II) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described. |
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