| Chemical modification and the photoluminescence stabilization of titanic acid nanotubes |
| |
| 作者姓名： | ZHANG Xingtang WANG Yumei ZHANG Chunmei JIANG Xiaohong TIAN Baoli LI Yuncai HUANG Yabin & DU Zuliang Key Laboratory for Special Functional Materials Henan University Kaifeng China Correspondence should be addressed to Du Zuliang |
| |
| 作者单位： | ZHANG Xingtang，WANG Yumei，ZHANG Chunmei，JIANG Xiaohong，TIAN Baoli，LI Yuncai，HUANG Yabin & DU Zuliang Key Laboratory for Special Functional Materials，Henan University，Kaifeng 457001，China Correspondence should be addressed to Du Zuliang |
| |
| 摘 要： | 1 Introduction In 1998, Kasuga et al. obtained a new kind of nanotubular materials by treating anatase TiO2 power with concentrated NaOH aqueous solution1,2]. This work soon aroused general concern due to their exten- sive applications in the photoelectr…
|
| 收稿时间： | 14 January 2005 |
| 修稿时间： | 15 March 2005 |
Chemical modification and the photoluminescence stabilization of titanic acid nanotubes |
| |
| ZHANG Xingtang,WANG Yumei,ZHANG Chunmei,JIANG Xiaohong,TIAN Baoli,LI Yuncai,HUANG Yabin & DU Zuliang Key Laboratory for Special Functional Materials,Henan University,Kaifeng ,China Correspondence should be addressed to Du Zuliang.Chemical modification and the photoluminescence stabilization of titanic acid nanotubes[J].Science in China(Chemistry),2006,49(2):155-161. |
| |
| Authors: | ZHANG Xingtang WANG Yumei ZHANG Chunmei JIANG Xiaohong TIAN Baoli LI Yuncai HUANG Yabin DU Zuliang |
| |
| Institution: | Key Laboratory for Special Functional Materials, Henan University, Kaifeng 457001, China |
| |
| Abstract: | Titanic acid nanotubes (H2Ti2O4(OH)2) were surface-modified with cetyl alcohol through dehydration reaction because of existence of Ti-OH. The modified nanotubes
were characterized by transmission electron microscopy (TEM), Fourier Transform Infrared (FT-IR) spectrometry and photoluminescence
(PL) spectra. The results indicate that the modified nanotubes can be easily dispersed into organic solvent such as chloroform
and toluene in contrast with the unmodified nanotubes, which makes it easier to be assembled by LB technique. Moreover, the
Ti-O-CH2(CH2)14CH3 on the surface of the nanotubes can hinder the adsorption of water and consequently the photoluminescence property of the
nanotubes can be stabilized. Even though kept in humid condition or in air for a long time, the modified nanotubes also maintain
the special photoluminescence property in the visible region. |
| |
| Keywords: | titanic acid nanotubes surface-modification photoluminescence |
| 本文献已被 CNKI 万方数据 SpringerLink 等数据库收录！ |
