Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution |
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| Authors: | Ikeda-Ohno Atsushi Tsushima Satoru Hennig Christoph Yaita Tsuyoshi Bernhard Gert |
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| Institution: | Institute of Resource Ecology, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstrasse 400, P.O. Box 510119, 01314 Dresden, Germany. a.ikeda@hzdr.de |
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| Abstract: | Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations. |
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