Helicity inversion from left- to right-handed square planar Pd(II) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism |
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| Authors: | Miyake Hiroyuki Ueda Masashi Murota Saori Sugimoto Hideki Tsukube Hiroshi |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. miyake@sci.osaka-cu.ac.jp |
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| Abstract: | A diastereomer pair of left- and right-handed square planar Pd(II) complexes was synthesized from a single chiral ligand as kinetic and thermodynamic products. Helicity inversion between the diastereomers occurred rapidly under thermal and microwave irradiation conditions. |
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