Phosphane Sulfide/Octacarbonyldicobalt-Catalyzed Pauson - Khand Reaction Under an Atmospheric Pressure of Carbon Monoxide |
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| Authors: | Hayashi Hashimoto Yamamoto Usuki Saigo |
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| Affiliation: | Department of Chemistry and Biotechnology Graduate School of Engineering, The University of Tokyo Hongo, Tokyo 113-8656 (Japan). |
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| Abstract: | Convenient access to cyclopentenones is provided by catalytic intra- and intermolecular Pauson - Khand reactions in the presence of octacarbonyldicobalt and tributylphosphane sulfide (see scheme). In contrast to other reactions of this type, they proceed under mild conditions (70 degrees C, 1 atm CO), and commercially available [Co(2)(CO)(8)] can be used without further purification. |
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