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Synthesis of cyclic sulfides
Authors:V I Dronov  V P Krivonogov
Institution:(1) Institute of Chemistry, Bashkirskii Branch, Academy of Sciences of the USSR, Ufa
Abstract:2,8-Dimethyl-1-thiahydrindan and 9-methyl-1-thiadecalin, respectively, were obtained by the reaction of 1-methyl-1-cyclohexene episulfide with allylmagnesium bromide and subsequent intramolecular cyclization of the resulting 1-methyl-2-allylcyclohexane-1-thiol by the action of sulfuric acid or UV irradiation. The cyclization proceeds stereospecifically.See 1] for communication V.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1186–1188, September, 1972.
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