Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors |
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| Authors: | Ivn Torres-Moya Alexandra Harbuzaru Beatriz Donoso Pilar Prieto Rocío Ponce Ortiz ngel Díaz-Ortiz |
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| Institution: | 1.Department of Inorganic, Organic Chemistry and Biochemistry, Faculty of Science and Chemical Technologies, University of Castilla-La Mancha-IRICA, 13071 Ciudad Real, Spain; (B.D.); (P.P.);2.Department of Physical Chemistry, Faculty of Sciences, University of Málaga, Campus of Teatinos s/n, 29071 Malaga, Spain; |
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| Abstract: | In this work, as an equivocal proof of the potential of microwave irradiation in organic synthesis, a complex pyrazine-decorated benzotriazole derivative that is challenging to prepare under conventional conditions has been obtained upon microwave irradiation, thus efficiently improving the process and yields, dramatically decreasing the reaction times and resulting in an environmentally friendly synthetic procedure. In addition, this useful derivative could be applied in organic electronics, specifically in organic field-effect transistors (OFETs), exhibiting the highest electron mobilities reported to date for benzotriazole discrete molecules, of around 10−2 cm2V−1s−1. |
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| Keywords: | microwave irradiation benzotriazole OFETs |
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