Vanadium-iron mixed trifluorides investigated by Mössbauer spectroscopy |
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Authors: | M. Tamine M. Leblanc J. M. Greneche |
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Affiliation: | (1) Equipe de Physique de l'Etat Condensé, U.R.A. CNRS 807, France;(2) Laboratoire des Fluorures, U.R.A. CNRS 449, Université du Maine, F-72017 Le Mans Cedex, France |
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Abstract: | Several solid solutions of the mixed crystalline Fe1–xVxF3 series, synthesized by the solid-state reaction, are investigated by Mössbauer spectroscopy. The evolution of the hyperfine structure as a function of temperature suggests that the Fe0.50V0.50F3 compound exhibits a spin-clustering phenomenon over the temperature range 70–175 K. We report here some preliminary high field Mössbauer spectra in order to discuss the magnetic behaviour. |
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