A new family of rare earth compounds,the ternary silicides RE2RhSi3 (RE = Y,La, Ce,Nd, Sm,Gd, Tb,Dy, Ho,Er) - crystal structure electrical and magnetic properties |
| |
Authors: | B Chevalier P Lejay J Etourneau P Hagenmuller |
| |
Institution: | Laboratoire de Chimie du Solide du CNRS, Université de Bordeaux I, 351, cours de la Libération, 33405 - Talence Cédex, France |
| |
Abstract: | New ternary silicides RE2RhSi3 (RE = Y, La, Ce, Nd, Sm, Gd, Tb, Dy, Ho, Er) have been prepared. They crystallize with a hexagonal symmetry structure which is derived from the AlB2-type. Si and Rh atoms are inside RE6 distorted trigonal prisms and are ordered in a two dimensional sublattice perpendicular to the c axis. The a and c parameters are approximately twice those of the corresponding disilicides RESi2. La2RhSi3 and Y2RhSi3 are not superconducting down to 1.6 K. Nd2RhSi3 is ferromagnetic at 15 K, but the other silicides order antiferromagnetically with metamagnetic phase transitions for certain of them. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|