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Determination of the formation rate constant of carrier-free111In(III) with EDTA
Authors:T Omori  R Kimizuka  K Yoshihara  M Yagi
Institution:(1) Department of Chemistry, Faculty of Science, Tohoku University, Aramaki-Aoba, 980 Sendai, (Japan);(2) Laboratory of Nuclear Science, Tohoku University, Mikamine, 982 Sendai, (Japan)
Abstract:The kinetics of reaction of indium(III)ion with EDTA (H4 edta) has been studied in aqueous acidic solutions using carrier-free111In and low concentrations of EDTA. The reaction takes place predominatly between indium(III) and H3 edta. The rate constant k3 is determined to be k3=(1.3±0.1)·105 dm3 mol–1 s–1 (25 °C).
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