Mössbauer, X-ray, electrical and magnetic properties of lithium borosilicate glasses containing iron and manganese Part I. Mössbauer measurements |
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| Authors: | A. A. Soliman H. Farouk I. Kashif A. M. Sanad |
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| Affiliation: | (1) Physics Department, Faculty of Science, Al-Azhar University, 11884 Nasr-city, Cairo, Egypt;(2) Physics Department, Faculty of Girls, Ain Shams University, Cairo, Egypt |
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| Abstract: | The effect of the replacement of MnO2 by Fe2O3 on the oxidation states of iron in some lithium borosilicate glasses were studied using Mössbauer spectroscopy. DTA and infrared measurements showed the presence of two glassy phases, one of them containing iron and the other manganese. The Mössbauer spectra were measured at room temperature for all the glass samples. The spectra revealed the presence of Fe ions only in ferric state in both tetrahedral and octahedral coordination. Also, it was observed that the ratio between the number of iron ions in both coordination states has not changed with the increase of MnO2 content. |
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