LiCl-LiBr-LiVO3 and LiCl-LiBr-Li2MoO4 ternary systems |
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Authors: | T V Gubanova E I Frolov and I K Garkushin |
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Institution: | (1) State Institution of Higher Professional Education Samara State Technical University, ul. Galaktionovskaya 141, Samara, 443010, Russia |
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Abstract: | Phase equilibria in the LiCl-LiBr-LiVO3 and LiCl-LiBr-Li2MoO4 ternary systems have been investigated by differential thermal analysis. The following compositions have been revealed (mol
%): eutectic in the LiCl-LiBr-LiVO3 system (18.0% LiCl, 72.0% LiBr, and 10.0% LiVO3) with a melting point of 464°C and specific enthalpy of melting of 213 kJ/kg, and a minimum in the LiCl-LiBr-Li2MoO4 system (27.0% LiCl, 48.0% LiBr, and 25.0% Li2MoO4) with a melting point of 444°C. The investigation of ternary systems including salts of alkali metals is of practical interest
for chemical industry and metallurgy, where salt mixtures are used as fused electrolytes and heat carriers.
Original Russian Text ? T.V. Gubanova, E.I. Frolova, I.K. Garkushin, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009,
Vol. 54, No. 7, pp. 1220–1223. |
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