| 氮自由基启动的1,n-烯炔环化反应 |
| |
| 引用本文： | 魏文廷,李强,张明忠,何卫民. 氮自由基启动的1,n-烯炔环化反应[J]. 催化学报, 2021, 42(5): 731-742. DOI: 10.1016/S1872-2067(20)63702-0 |
| |
| 作者姓名： | 魏文廷 李强 张明忠 何卫民 |
| |
| 作者单位： | 宁波大学材料科学与化学工程学院, 新型功能材料与制备科学国家重点实验室培育基地, 浙江宁波315211;宁波大学材料科学与化学工程学院, 新型功能材料与制备科学国家重点实验室培育基地, 浙江宁波315211;聊城大学化学化工学院, 功能有机分子和材料研究所, 山东聊城252059;长江师范学院化学化工学院, 重庆408100;长沙理工大学电力与交通材料保护湖南省重点实验室, 湖南长沙410114 |
| |
| 基金项目： | This work was supported by the National Natural Science Foundation of China ;湖南省自然科学基金;and the Hunan Provincial Natural Science Foundation of China ;国家自然科学基金;浙江省省属高校基本科研业务费专项资金;the Fundamental Research Funds for the Provincial Universities of Zhejiang |
| |
| 摘 要： | C-N键广泛存在于药物、天然产物和功能材料中,而氮中心自由基在C-N键的构建中起到关键作用.但是,与广泛使用的碳中心自由基相比,氮中心自由基由于缺乏实用简便的产生方法而尚未得到充分研究.因此,发展高效的氮中心自由基引发反应迫在眉睫.在过去的几年里,得益于可信赖且可控制的自由基化学的兴起,可以通过热分解、氧化剂促进、金属...
|
| 关 键 词： | 1,n-烯炔 氮自由基 环化 C-N键 |
N-Radical enabled cyclization of 1,n-enynes |
| |
| Wen-Ting Wei,Qiang Li,Ming-Zhong Zhang,Wei-Min He. N-Radical enabled cyclization of 1,n-enynes[J]. Chinese Journal of Catalysis, 2021, 42(5): 731-742. DOI: 10.1016/S1872-2067(20)63702-0 |
| |
| Authors: | Wen-Ting Wei Qiang Li Ming-Zhong Zhang Wei-Min He |
| |
| Affiliation: | (State Key Laboratory Base of Novel Functional Materials and Preparation Science,School of Materials Science and Chemical Engineering,Ningbo University,Ningbo 315211,Zhejiang,China;Institution of Functional Organic Molecules and Materials,School of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng 252059,Shandong,China;School of Chemistry and Chemical Engineering,Yangtze Normal University,Chongqing 408100,China;Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation,Changsha University of Science and Technology,Changsha 410114,Hunan,China) |
| |
| Abstract: | Compared to the widely used carbon-centered radicals, N-radicals have been relatively unexplored owing to the lack of practical and convenient production methods. Over the past few years, benefit-ting from the resurgence of reliable and controllable radical chemistry, N-radicals have been pro-duced via thermal decomposition, oxidants, metal salts, or electrocatalysis. Therefore, numerous N-radical enabled cyclization of 1,n-enynes methods have been developed, providing a versatile and concise synthetic platform for the preparation of complex cyclic systems and natural products con-taining elaborate ring frameworks. In this review, we will summarize recent advances in the prom-ising field of radical chemistry focusing on the production methods of N-radicals and their cycliza-tion patterns, associated mechanisms, unmet challenges, and future opportunities. |
| |
| Keywords: | 1 n-Enynes N-Radical Cyclization C-N bond |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
