一维链状化合物[Ag(L)]·H2O的合成、晶体结构和荧光性质 |
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引用本文: | 邓奕芳,谭雄文,张春华,邝代治,陈满生.一维链状化合物[Ag(L)]·H2O的合成、晶体结构和荧光性质[J].无机化学学报,2010,26(5):909-912. |
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作者姓名: | 邓奕芳 谭雄文 张春华 邝代治 陈满生 |
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作者单位: | 功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学系,衡阳 421008,功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学系,衡阳 421008,功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学系,衡阳 421008,功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学系,衡阳 421008,功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学系,衡阳 421008 |
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摘 要: | The title compound, Ag(L)]·H2O,1, where HL=4-(isonicotinamido)benzoic acid, was synthesized in methanol solution and its crystal structure was determined by X-ray diffraction analysis. The crystal is of monoclinic, space group P21/c with a=0.571 8(8) nm, b=1.357 2(18) nm, c=1.558 0(2) nm, β=91.090(2)°, V=1.209 0(3) nm3, Z=4, Dc=2.009 g·cm-3, F(000)=722, Rint=0.042 9, R=0.027 1, wR=0.055 6. In complex 1, the Ag atoms are linearly coor-dinated by one O atom and one N atom of two ligand molecules. Each L- ligand in turn uses its one carboxylate group and one pyridinyl groups to connect two metal centers, then the one-dimensional (1D) chains is formed. On the other hand, the 1D chains are further connected by O1W-H1WB…O2 hydrogen bonds and Ag-O weak interactions to give a two-dimensional (2D) layer, finally, the 2D net extents to three-dimensional (3D) supramolecular framework by O1W-H1WB…O1 as well as N2-H2…O2 interactions. CCDC: 762259.
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关 键 词: | 银配合物 晶体结构 氢键 荧光性质 |
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