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Complex of Copper(II) with Ethylenediamine and Decyl Sulfate Ions. Formation in Water and Crystal Structure
Authors:Amirov  R R  Litvinov  I A  Gubaidullin  A T  Matyugicheva  U V
Institution:(1) Kazan State Uiversity, Kazan, Tatarstan, Russia;(2) Arbuzov Insitute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatrstan, Russia
Abstract:Decyl sulfate ions form strong associates with ethylenediammonium cations and copper(II) ethylenediamine complexes. A solid compound of the composition copper(II):ethylenediamine:decyl sulfate ion = 1:2:2 was isolated from the aqueous solution; its crystal structure was studied to find that it comprises a regular combination of formula units of an inner-sphere complex bis(ethylenediamine)bis(decyl sulfato)copper(II) and a complex associate of two decyl sulfate ions with diaquabis(ethyenediamine)copper(II).
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