Structural investigation of Te-based chalcogenide glasses using Raman spectroscopy |
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| Authors: | Jie Sun Qiuhua Nie Xunsi Wang Shixun Dai Xianghua Zhang Bruno Bureau Catherine Boussard Clément Conseil Hongli Ma |
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| Institution: | 1. Laboratoire Verres et Céramiques UMR-CNRS 6226, University of Rennes, 1 35042 Rennes Cedex, France;2. Department of Optoelectronics and Informational Technologies, Ivan Franko National University of Lviv 50, Dragomanova Str., Lviv 79005, Ukraine;3. Department of Physics & Astronomy, Austin Peay State University, Clarksville, TN 37044, USA;4. Department of Inorganic Chemistry, Ivan Franko National University of Lviv 6, Kyryla & Mefodiya Str., Lviv 79005, Ukraine;1. Department of Materials Science and Engineering, Korea Aerospace University, Gyeonggi 412-791, Republic of Korea;2. Transparent Transducer and UX Creative Research Center, Electronics and Telecommunications Research Institute, Daejeon 305-700, Republic of Korea;3. Department of Materials Science and Engineering, Pohang University of Science and Technology, Gyeongbuk 790-784, Republic of Korea;4. Ultra Precision Optics Research Center, Korea Photonics Technology Institute, Gwangju 500-779, Republic of Korea |
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| Abstract: | Structural changes of metals (Zn, Sb, In, Ga) and metal halides (AgI, ZnI2, CdI2, PbI2, BiI3) modified GeTe4 glasses were investigated with the aid of Raman spectroscopy. The Raman spectra of these glasses in the frequency region between 100 cm?1 and 300 cm?1 display four main bands at about 124, 140, 159 and 275 cm?1 which are contributed by Ge–Te, Te–Te, Te–Te and Ge–Ge vibration modes. The intensity of 159 cm?1 and 275 cm?1 bands vary with the addition of different glass modifiers. While the relative intensity of the 124 cm?1 and 140 cm?1 bands are insensitive to composition changes. Glass modifiers like Zn, In and Sb act as glass network unstabilizer which will disorganize the glass network by opening up the chain structures of Ge–Te and Te–Te. In the case of Ga and metal halides, Ga can open up Ge–(Te–Te)4/2 tetrahedra and form Ga–(Te–Te)3/2 triangle. Iodine can form covalent bonds with tellurium and decrease the tendency of microcrystal formation. Thus both Ga and iodine ultimately act as glass network stabilizer. |
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