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| 保留指数结合准确质量测定对鱼腥草挥发性成分的定性分析 | |
| 引用本文： | 刘素红,王呈仲,苏越,郭寅龙. 保留指数结合准确质量测定对鱼腥草挥发性成分的定性分析[J]. 分析测试学报, 2010, 29(2). DOI: 10.3969/j.issn.1004-4957.2010.02.005 |
| 作者姓名： | 刘素红 王呈仲 苏越 郭寅龙 |
| 作者单位： | 1. 上海中医药大学,中医复杂系统研究中心,上海,201203;中国科学院上海有机化学研究所,上海质谱中心,上海,200032 2. 上海中医药大学,中医复杂系统研究中心,上海,201203 3. 中国科学院上海有机化学研究所,上海质谱中心,上海,200032 |
| 基金项目： | 国家自然科学基金资助项目，上海市教育委员会科研创新项目，上海市自然科学基金资助项目，烟草专卖局资助项目 |
| 摘 要： | 采用顶空-气相色谱-四极质谱法和顶空-气相色谱-飞行时间质谱法对鱼腥草挥发性成分进行检测,运用保留指数结合准确质量测定,分别从鱼腥草茎和叶中鉴定出49、39种挥发性组分,并采用峰面积归一化法测定各组分的相对含量。鱼腥草茎和叶中的挥发性成分差别较大。鱼腥草茎以α-蒎烯(12.24%)、β-蒎烯(22.42%)、月桂烯(11.98%)、乙酸冰片酯(10.97%)、甲基正壬酮(10.83%)为主要成分,而鱼腥草叶则以月桂烯(39.48%)、(Z)-β-罗勒烯(26.52%)、癸醛(10.35%)、桧烯(4.43%)、甲基正壬酮(2.44%)为主。结合保留指数和准确质量测定能显著提高质谱定性的准确性,有利于解决质谱检索时定性不确定的问题。 |
| 关 键 词： | 保留指数 准确质量测定 鱼腥草 挥发性成分 |
Qualitative Analysis of Volatile Compounds from Houttuynia cordata Thunb by Retention Index and Accurate Mass Measurement |
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| LIU Su-hong,,WANG Cheng-zhong,SU Yue,GUO Yin-long. Qualitative Analysis of Volatile Compounds from Houttuynia cordata Thunb by Retention Index and Accurate Mass Measurement[J]. Journal of Instrumental Analysis, 2010, 29(2). DOI: 10.3969/j.issn.1004-4957.2010.02.005 | |
| Authors: | LIU Su-hong WANG Cheng-zhong SU Yue GUO Yin-long |
| Affiliation: | LIU Su-hong1,2,WANG Cheng-zhong1,SU Yue1,GUO Yin-long2(1.Research Center for Traditional Chinese Medicine Complexity System,Shanghai University of Traditional Chinese Medicine,Shanghai 201203,China,2.Shanghai Mass Spectrometry Center,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China) |
| Abstract: | A static headspace-gas chromatography-quadrupole mass spectrometry(HS-GC-QMS) and static headspace-gas chromatography-time of flight mass spectrometry(HS-GC-TOF MS) have been utilized to analyze volatile compounds from fresh Houttuynia cordata Thunb.49 and 39 volatile compounds were identified in the stems and leaves of Houttuynia cordata Thunb,respectively,by combination of retention index and accurate mass measurement.The relative content of each constituent was determined by area normalization.Among thes... |
| Keywords: | GC-MS retention index accurate mass measurement Houttuynia cordata Thunb volatile com-pounds GC-MS |
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