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Oxidative polymerization of N-substituted carbazoles
Authors:A Sezai Sarac  Esma Sezer  Belkis Ustamehmetoglu
Abstract:Poly(N-vinylcarbazole), poly(N-carbazole) and poly(N-ethylcarbazole) powders were chemically synthesized by the reaction of ceric ammonium nitrate (CAN) with N-vinylcarbazole carbazole and N-ethylcarbazole in acetonitrile. Products were characterized by elemental analysis, Fourier transform infrared spectroscopy, scanning electron microscopy and viscosity, X-ray fluorescence and four-probe conductivity measurement. It is found that when a suitable concentration of CAN is used in the polymerization process, the conductivity of chemically synthesized polymers can be improved further by controlling the CAN addition. © 1997 John Wiley & Sons, Ltd.
Keywords:oxidative polymerization  N-vinylcarbazole  carbazole  N-ethylcarbazole  ceric ammonium nitrate  conductive polycarbazoles
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