Abstract: | Poly(arylene ether)s ( 3 ), ( 4 ) containing pendant benzoyl groups as precursors for novel polyxanthenes ( 7 ), ( 8 ) were prepared by nucleophilic substitution reaction of 2,5-difluoro-4-benzoylbenzophenone ( 1 ) or 2,5-difluoro-4-(4-dodecylbenzoyl)-4′-dodecylbenzophenone ( 2 ) with hydroquinone derivatives in the presence of potassium carbonate in N,N-dimethylacetamide. The polycondensation proceeded smoothly at 165°C and produced poly(arylene ether)s with inherent viscosities up to 0.80 dL/g. The novel polyxanthenes were synthesized via the reduction of poly(arylene ether)s followed by the Friedel-Crafts cyclization of diol polymers. The structure of the polyxanthenes was characterized by 1H-NMR and IR spectroscopies. Polyxanthene 8 was quite soluble in chloroform and THF. The 10% weight loss temperature of polyxanthene 7 was 510°C in nitrogen and it was 90°C higher than the corresponding poly(arylene ether) 3 . © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35 : 2267–2272, 1997 |