Epitaxial recrystallization of HDPE-quenched ultrathin films on oriented iPP substrates |
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Authors: | Shouke Yan,Jü rgen Petermann,Decai Yang |
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Abstract: | The recrystallization behavior of high-density polyethylene (HDPE) on the highly oriented isotactic polypropylene (iPP) substrates at temperatures below the melting temperature of HDPE has been investigated by means of transmission electron microscopy. The results obtained by the bright-field observation and the electron diffraction show that upon annealing the HDPE-quenched films on the oriented iPP substrates at temperatures below 125°C, only a small amount of HDPE recrystallizes on the iPP substrate with [001]HDPE//[001]iPP, while annealing the HDPE-quenched films at temperatures above 125°C, all of the HDPE crystallites recrystallize epitaxially on the iPP substrate with [001]HDPE//[101]iPP. © 1997 John Wiley & Sons, Inc. J Polym Sci B: 35 : 1415–1421, 1997 |
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Keywords: | epitaxy recrystallization high-density polyethylene isotactic polypropylene morphology |
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