| Photoinduced Electron Transfer (PET) between C_(60) and Amines in Micelle Solution A Kinetic ESR Study |
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| 作者姓名： | Jian SUN Yang LIU* De Wen CHEN Qi Yuan ZHANG State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing |
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| 作者单位： | Jian SUN，Yang LIU*，De Wen CHEN，Qi Yuan ZHANG State Key Laboratory for Structural Chemistry of Unstable and Stable Species，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080 |
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| 基金项目： | State Key Plan for National Natural Science，国家自然科学基金 |
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| 摘 要： | Fullerene chemistry has been one of the most exciting research subjects in the recent decade1,2. However, the predominant hydrophobic character and the spherical carbon allotrope of C60 hinder its solubility in an aqueous solution. In order to efficiently slow down charge recombination in the PET system containing C60, water was selected as optimal polar media to stabilize charge separation state. Accordingly, solubility of fullerene in water had to be achieved by incorporating it into th…
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Photoinduced Electron Transfer (PET) between C60 and Amines in Micelle Solution - A Kinetic ESR Study |
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| Jian SUN,Yang LIU*,De Wen CHEN,Qi Yuan ZHANG State Key Laboratory for Structural Chemistry of Unstable and Stable Species,Institute of Chemistry,Chinese Academy of Sciences,Beijing .Photoinduced Electron Transfer (PET) between C_(60) and Amines in Micelle Solution A Kinetic ESR Study[J].Chinese Chemical Letters,2002,13(1). |
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| Authors: | Jian Sun Yang LIU De Wen CHEN Qi Yuan ZHANG |
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| Abstract: | As indicated by kinetic ESR measurements, the key factor to affect electron recombination in the process of PET between C60 and amines is the space between donor and C60. To increase solubility of C60 in water, it was incorporated into micelle of surfactants. ] |
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| Keywords: | C60 ESR photoinduced electron transfer (PET) micelle |
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