| Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks [Mn(PDC)H2O]n |
| |
| 作者姓名： | GAO En-Jun GU Xiao-Fu SUN Ya-Guang YIN Hong-Xi WU Qiong LIU Lei ZHU Ming-Chang ZHANG Wan-Zhong |
| |
| 作者单位： | Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang, ;Liaoning 110142, China ; |
| |
| 摘 要： | A novel coordination polymer, Mn(PDC)H2O]n (1) (H2PDC＝pyridine-2,3-dicarboxylic acid), has been hydrothermally synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed, and further assembled into a three-dimensional supramolecular structure bridged by PDC ligands. Moreover, the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(II) centers within the chains and even weak ferromagnetic interactions between the Mn(II) centers in different chains.
|
| 关 键 词： | manganese(II) coordination polymer crystal structure magnetic property |
| 收稿时间： | 2007-12-19 |
| 修稿时间： | 2008-3-18 |
Synthesis,Crystal Structure and Magnetic Properties of Novel Three‐dimensional Frameworks [Mn(PDC)H2O]n |
| |
| GAO En-Jun,GU Xiao-Fu,SUN Ya-Guang,YIN Hong-Xi,WU Qiong,LIU Lei,ZHU Ming-Chang,ZHANG Wan-Zhong.Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks [Mn(PDC)H2O]n[J].Chinese Journal of Chemistry,2008,26(11):2133-2136. |
| |
| Authors: | En‐Jun GAO Xiao‐Fu GU Ya‐Guang SUN Hong‐Xi YIN Qiong WU Lei LIU Ming‐Chang ZHU Wan‐Zhong ZHANG |
| |
| Institution: | 1. Tel.: 0086‐024‐89385016;2. Fax: 0086‐024‐89388211;3. Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang, Liaoning 110142, China |
| |
| Abstract: | |
| |
| Keywords: | manganese(II) coordination polymer crystal structure magnetic property |
|
| 点击此处可从《中国化学》浏览原始摘要信息 |
| 点击此处可从《中国化学》下载免费的PDF全文 |
|
