| 利用甘油废水Pt/TiO2光催化制氢 |
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| 引用本文： | 李敏,李越湘,彭绍琴,吕功煊,李树本.利用甘油废水Pt/TiO2光催化制氢[J].分子催化,2008,22(2):166-171. |
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| 作者姓名： | 李敏 李越湘 彭绍琴 吕功煊 李树本 |
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| 作者单位： | 1. 南昌大学,化学系,江西,南昌,330047
2. 中国科学院兰州化学物理研究所 |
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| 基金项目： | 国家重点基础研究发展计划(973计划)
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国家自然科学基金
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江西省自然科学基金 |
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| 摘 要： | 研究了以甘油为电子给体在Pt/TiO2上光催化生成氢的反应.结果表明甘油能显著地提高光催化放氢效率,并且其自身的降解活性也很好.研究了反应时间、甘油起始浓度、溶液pH值、甘油废水中共存物对光催化放氢的影响.甘油光催化降解最终产物是H2O和CO2,检测到了甘油醛、羟基乙醛、羟基乙酸、甲醛等中间产物.探讨了可能的反应机理.
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| 关 键 词： | 光催化 制氢 甘油 降解 |
| 文章编号： | 1001-3555(2008)02-0166-06 |
| 修稿时间： | 2007年7月31日 |
Photocatalytic Hydrogen Generation Using Glycerol Wastewater over Pt/TiO2 |
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| LI Min,LI Yue-xiang,PENG Shao-qin,LU Gong-xuan,LI Shu-ben.Photocatalytic Hydrogen Generation Using Glycerol Wastewater over Pt/TiO2[J].Journal of Molecular Catalysis (China),2008,22(2):166-171. |
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| Authors: | LI Min LI Yue-xiang PENG Shao-qin LU Gong-xuan LI Shu-ben |
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| Abstract: | Using glycerol as electron donor, the photocatalytic hydrogen generation over Pt/TiO2 has been investigated. The results show that glycerol can not only improve the efficiency of photocatalytic hydrogen generation but also be decomposed effectively. The factors which affect photocatalytic hydrogen generation, such as irradiation time, initial concentrations of the glycerol solution, pH-value of the suspensions and the coexisting substances were stu-died. The final products of glycerol oxidation were H2O and CO2. Glycoladehyde, glycolic acid, formaldehyde were identified as the intermediate products. A possible reaction mechanism was discussed. |
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| Keywords: | Photocatalysis Hydrogen generation Glycerol Degradation |
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