| 衣康酸系铜离聚体引发下的甲基丙烯酸甲酯聚合反应 |
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| 引用本文： | 王洪祚,廖冬生,王颖. 衣康酸系铜离聚体引发下的甲基丙烯酸甲酯聚合反应[J]. 高分子学报, 1993, 0(6): 641-647 |
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| 作者姓名： | 王洪祚 廖冬生 王颖 |
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| 作者单位： | 武汉大学化学系，武汉大学化学系，武汉大学化学系 武汉，邮政编码:430072，武汉，邮政编码:430072，武汉，邮政编码:430072 |
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| 摘 要： | 本文报道了衣康酸系铜离聚体引发下的甲基丙烯酸甲酯(MMA)聚合反应,对影响反应的各种因素、反应机理及反应动力学进行了研究。
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| 关 键 词： | 铜离聚体 衣康酸单乙酯-丙烯酸丁酯共聚物 自由基加聚反应 聚合反应动力学 |
| 收稿时间： | 1991-07-10 |
STUDIES ON THE POLYMERIZATION OF MMA INITIATED BY THE Cu(Ⅱ)IONOMERS BASED ON ITACONATE |
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| WANG Hong-zuo,LIAO Dong-sheng,WANG Ying. STUDIES ON THE POLYMERIZATION OF MMA INITIATED BY THE Cu(Ⅱ)IONOMERS BASED ON ITACONATE[J]. Acta Polymerica Sinica, 1993, 0(6): 641-647 |
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| Authors: | WANG Hong-zuo LIAO Dong-sheng WANG Ying |
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| Affiliation: | Department of Chemistry; Wuhan University; Wuhan; Post code: 430072 |
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| Abstract: | The Cu (Ⅱ)-ionomers based on itaconate can initiate the polymerization of MMA in the presence of CC14. Its free radical polymerization mechanism was demonstrated and the effects of various reaction conditions on the rate of polymerization, conversion and molecular weight were studied. The kinetic equation of polymerization can be expressed as Rp = Ke-67235/RT (Ionomer)0.04 (MMA)1.34(CCl4)ns(in this experiment m=0. 5-3) |
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| Keywords: | Cu( I )-Ionomer Monoester itaconate Free radical polymerization Kinetics of polymerization |
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