Platinum-catalysed bisindolylation of allenes: a complementary alternative to gold catalysis |
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| Authors: | Muñoz María Paz de la Torre María C Sierra Miguel Angel |
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| Institution: | School of Chemistry, University of East Anglia, Earlham Road, Norwich, NR4 7TJ, UK. M.Munoz-Herranz@uea.ac.uk |
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| Abstract: | Pt versus Au: Platinum-catalysed addition of nucleophiles to allenes follows a distinctly different pathway to the process catalysed by gold(I) complexes; the platinum catalyst leads to different products with indoles involving a bisindolylation reaction, whereas gold(I) gives allyl indoles from a single addition (see scheme). |
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