Kinetics of reduction of tris(4,4,4-trifluoro-1-(2-thienyl)-butane-1,3-dionato)ruthenium(III) in methanol |
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| Authors: | R Grobelny and B Bana |
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| Institution: | (1) Institute of Chemistry, University of Wroclaw, 50-383 Wroclaw, Poland;(2) Present address: Department of Chemistry, Rivers State University Science and Technology, PMB 5080, Port-Harcurt, Nigeria |
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| Abstract: | Reduction of tris(4,4,4-trifluoro-1-(2-thienyl)-butane-1,3-dionato) ruthenium(III) in methanol solution containing potassium hydroxide has been studied kinetically. The results suggest outer-sphere complex formation between ruthenium(III) species and methoxide anion.
                (4,4,4-  -1-(2-)- -1,3)(III)     .       ,   -.
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