Kinetics of reduction of tris(4,4,4-trifluoro-1-(2-thienyl)-butane-1,3-dionato)ruthenium(III) in methanol |
| |
Authors: | R Grobelny and B Bana |
| |
Institution: | (1) Institute of Chemistry, University of Wroclaw, 50-383 Wroclaw, Poland;(2) Present address: Department of Chemistry, Rivers State University Science and Technology, PMB 5080, Port-Harcurt, Nigeria |
| |
Abstract: | Reduction of tris(4,4,4-trifluoro-1-(2-thienyl)-butane-1,3-dionato) ruthenium(III) in methanol solution containing potassium hydroxide has been studied kinetically. The results suggest outer-sphere complex formation between ruthenium(III) species and methoxide anion.
![Icy](/content/wg636t456351p0kp/xxlarge1048.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![dcy](/content/wg636t456351p0kp/xxlarge1076.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![mcy](/content/wg636t456351p0kp/xxlarge1084.gif) ![pcy](/content/wg636t456351p0kp/xxlarge1087.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) (4,4,4-![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![fcy](/content/wg636t456351p0kp/xxlarge1092.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) -1-(2-![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) )-![bcy](/content/wg636t456351p0kp/xxlarge1073.gif) ![ucy](/content/wg636t456351p0kp/xxlarge1091.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![dcy](/content/wg636t456351p0kp/xxlarge1076.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) -1,3)![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![ucy](/content/wg636t456351p0kp/xxlarge1091.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) (III) ![mcy](/content/wg636t456351p0kp/xxlarge1084.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![softcy](/content/wg636t456351p0kp/xxlarge1100.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![shchcy](/content/wg636t456351p0kp/xxlarge1097.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![chcy](/content/wg636t456351p0kp/xxlarge1095.gif) . ![Ncy](/content/wg636t456351p0kp/xxlarge1053.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![pcy](/content/wg636t456351p0kp/xxlarge1087.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![ucy](/content/wg636t456351p0kp/xxlarge1091.gif) ![chcy](/content/wg636t456351p0kp/xxlarge1095.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ycy](/content/wg636t456351p0kp/xxlarge1099.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![zcy](/content/wg636t456351p0kp/xxlarge1079.gif) ![ucy](/content/wg636t456351p0kp/xxlarge1091.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![softcy](/content/wg636t456351p0kp/xxlarge1100.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![mcy](/content/wg636t456351p0kp/xxlarge1084.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![zhcy](/content/wg636t456351p0kp/xxlarge1078.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![zcy](/content/wg636t456351p0kp/xxlarge1079.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![yucy](/content/wg636t456351p0kp/xxlarge1102.gif) ![chcy](/content/wg636t456351p0kp/xxlarge1095.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) , ![chcy](/content/wg636t456351p0kp/xxlarge1095.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![mcy](/content/wg636t456351p0kp/xxlarge1084.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![tscy](/content/wg636t456351p0kp/xxlarge1094.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![bcy](/content/wg636t456351p0kp/xxlarge1073.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![zcy](/content/wg636t456351p0kp/xxlarge1079.gif) ![ucy](/content/wg636t456351p0kp/xxlarge1091.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![pcy](/content/wg636t456351p0kp/xxlarge1087.gif) ![rcy](/content/wg636t456351p0kp/xxlarge1088.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![mcy](/content/wg636t456351p0kp/xxlarge1084.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![zhcy](/content/wg636t456351p0kp/xxlarge1078.gif) ![ucy](/content/wg636t456351p0kp/xxlarge1091.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![chcy](/content/wg636t456351p0kp/xxlarge1095.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ycy](/content/wg636t456351p0kp/xxlarge1099.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![dcy](/content/wg636t456351p0kp/xxlarge1076.gif) ![dcy](/content/wg636t456351p0kp/xxlarge1076.gif) ![ucy](/content/wg636t456351p0kp/xxlarge1091.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![dcy](/content/wg636t456351p0kp/xxlarge1076.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![vcy](/content/wg636t456351p0kp/xxlarge1074.gif) ![acy](/content/wg636t456351p0kp/xxlarge1072.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![gcy](/content/wg636t456351p0kp/xxlarge1075.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![mcy](/content/wg636t456351p0kp/xxlarge1084.gif) ![pcy](/content/wg636t456351p0kp/xxlarge1087.gif) ![lcy](/content/wg636t456351p0kp/xxlarge1083.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) ![mcy](/content/wg636t456351p0kp/xxlarge1084.gif) ![iecy](/content/wg636t456351p0kp/xxlarge1077.gif) ![tcy](/content/wg636t456351p0kp/xxlarge1090.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![kcy](/content/wg636t456351p0kp/xxlarge1082.gif) ![scy](/content/wg636t456351p0kp/xxlarge1089.gif) -![icy](/content/wg636t456351p0kp/xxlarge1080.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) ![ncy](/content/wg636t456351p0kp/xxlarge1085.gif) ![ocy](/content/wg636t456351p0kp/xxlarge1086.gif) .
|
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|