| NaB5O8·5H2O过饱和溶液中硼氧配阴离子的FT-IR光谱分析 |
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| 引用本文： | 贾永忠,高世扬,夏树屏,李军. NaB5O8·5H2O过饱和溶液中硼氧配阴离子的FT-IR光谱分析[J]. 无机化学学报, 1999, 15(6): 766-772 |
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| 作者姓名： | 贾永忠 高世扬 夏树屏 李军 |
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| 作者单位： | 兰州大学化学系， 兰州 730000;中国科学院盐湖研究所西安二部， 西安 710043,兰州大学化学系， 兰州 730000;中国科学院盐湖研究所西安二部， 西安 710043,中国科学院盐湖研究所西安二部， 西安 710043,中国科学院盐湖研究所西安二部， 西安 710043 |
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| 摘 要： | 研究了NaB5O8·5H2O过饱和水溶液及其在稀释和酸化过程中的FT-IR光谱，并与已知固体五硼酸盐对比进行光谱频率的归属，提出五硼酸盐过饱和水溶液中硼氧配阴离子的存在形式及其相互转化机理。
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| 关 键 词： | 五水合五硼酸钠 过饱和溶液 FT-IR光谱 多聚硼氧配阴离子 |
FT-IR SPECTROSCOPIC STUDY OF BORATE IN SUPERSATURATED SOLUTON OF SODIUM PENTABORATE |
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| JIA Yong-Zhong,GAO Shi-Yang,XIA Shu-Ping and LI Jun. FT-IR SPECTROSCOPIC STUDY OF BORATE IN SUPERSATURATED SOLUTON OF SODIUM PENTABORATE[J]. Chinese Journal of Inorganic Chemistry, 1999, 15(6): 766-772 |
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| Authors: | JIA Yong-Zhong GAO Shi-Yang XIA Shu-Ping LI Jun |
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| Abstract: | FT-IR spectra of different boron-containing supersaturated aqueous solutions of sodium borate have been obtained and during acidification, the supersaturated solution that react with different amount of azeotropic hydrochloric acid was recorded by FT-IR spectroscope and pH meter respectively. The recorded frequencies of the borate aqueous solution subtract that of water as a blank value and their assignments were given. The results showed that there might exist various polyborate anions in the supersaturated solution and the transformation mechanism of polyborate ions was discussed. |
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| Keywords: | sodium pentaborate supersaturated solution FT-IR spectra polyborate ions |
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