Tris(1-adamantanecarboxylato)bismuth(III): Synthesis and structure |
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| Authors: | V. V. Sharutin I. V. Egorova O. K. Sharutina L. A. Nevmeshkina |
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| Affiliation: | (1) Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia |
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| Abstract: | Tris(1-adamantanecarboxylato)bismuth(III) was synthesized by reacting triphenylbismuth with 1-adamantanecarboxylic acid in toluene. The bismuth atom in tetramer {Bi[OC(O)C10H15]3}4 is coordinated by 10 oxygen atoms of bidentate-chelating and two types of chelate-bridging adamantanecarboxylate ligands (Bi-O, 2.191–2.955 and 3.634 Å). |
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