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Infrared reflectivity of MTPA (TCNQ)2 single crystals
Authors:J Petzelt  K Král  N Ryšavá  L Dobiášová  J Kroupa  J Oswald  A Szyszkowski  A Graja
Institution:Institute of Physics, Czech. Acad. Sci., 18040 Prague 8, Na Slovance 2, USSR;Institute of Molecular Physics, Polish Acad. Sci., 60-179 Poznaň, Poland
Abstract:Polarized infrared reflectivity of single crystal MTPA (TCNQ)2 was measured in the 40–4000 cm?1 region and evaluated to obtain the dielectric function and conductivity. For Eb polarization, a very strong coupling between TCNQ intramolecular vibrations and electronic motion is observed. The bare electronic absorption is modelled by a sum of two classical oscillators.
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