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Pre-resonant enhancement of the Raman scattering from KI:Tl+
Authors:Charles T Walker  Giorgio Benedek
Institution:Max-Planck-Institut für Festkörperforschung Heisenbergstr. 1, 7000 Stuttgart 80, F.R.G.
Abstract:Eg and T2g spectra at room and nitrogen temperature at several laser wavelengths are reported for KI:Tl+. As resonance with Tl+ -absorption bands is approached the optic phonon parts of the spectra are enhanced relative to the acoustic phonon parts, and distortions occur within the acoustic and optic parts of the spectra. A model for the scattering is employed which involves electron-phonon coupling to nearest and nn neighbors. Exchange and crystal field contributions to the electron-phonon coupling are distinguished.
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