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The application of metal-organic frameworks in electrocatalytic nitrogen reduction
Affiliation:1. Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, China;2. Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang 441053, China;3. Institute of Mathematics, Free University of Berlin, Berlin D-14195, Germany;1. College of Chemistry and Chemical Engineering, Key Laboratory of Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, 150025, China;2. Modern Experiment Center, Harbin Normal University, Harbin, 150025, China
Abstract:In recent years, the research of nitrogen reduction reaction (NRR) under ambient conditions has attracted wide attention for their relatively low energy consumption, in which rational design of electrocatalysts is the key to achieve high-performance NRR. Metal-organic frameworks (MOFs), as a new kind of porous material, have been intensively studied in the past few decades owing to not only their structural versatility and tunability but also intrinsic porosity. Due to their structural features, MOFs also have potential applications in mild condition electrocatalysis of NRR. In this review, the recently experimental and theoretical studies of MOFs in NRR electrocatalysts are briefly summarized.
Keywords:Nitrogen reduction reaction  Metal-organic frameworks  Electrocatalysis  Nanomaterials
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