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Achieving high yield of Ti3C2Tx MXene few-layer flakes with enhanced pseudocapacior performance by decreasing precursor size
Institution:1. School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China;2. Key Laboratory of Hunan Province for Efficient Power System and Intelligent Manufacturing, Shaoyang University, Shaoyang 422000, China;1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, State Key Laboratory of Urban Water Resource and Environment (SKLUWRE), School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, PR China;2. Engineering Department, Lancaster University, Lancaster LA1 4YW, UK;1. Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China;2. State Key Laboratory of Traction Power, Southwest Jiaotong University, Chengdu 610031, China;1. Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China;2. School of Engineering Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:Ti3C2Tx, a most studied member of MXene family, shows promise as a candidate electrode for pseudocapacitor due to its electronic conductivity and hydrophilic surface. However, the unsatisfactory yield of Ti3C2Tx few-layer flakes significantly restricted it in real applications. Here, we proposed a simple solution to boost the yield of Ti3C2Tx few-layer flakes by decreasing precursor size. When using the small 500 mesh Ti3AlC2 powders as raw material, high yield of 65% was successfully achieved. Moreover, the as-received small flakes also exhibit an enhanced pseudocapacior performance owing to their excellent electrical conductivity, expanded interlayer space and more O content on the surface. This work not only sheds light on the cost effective mass production of Ti3C2Tx few-layer flakes, but also provides an efficient solution for the design of MXene electrodes with high pseudocapacior performance.
Keywords:MXene  High yield  Pseudocapacitor  Precursor size  Flake size
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