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Metal-free synthesis of 1,2,3-benzotriazines
Affiliation:1. College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing 408000, China;2. Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha 410114, China;3. School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China;4. School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China;1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, China;2. Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China;3. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China;1. Key Laboratory of Biomedical Polymers, Engineering Research Centre of Organosilicon Compounds & Materials, Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China;2. Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055, China;3. School of Pharmaceutical Sciences (Shenzhen), Sun Yat-sen University, Shenzhen 518107, China;1. College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing 408000, China;2. School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China;3. Department of Chemistry, Hunan University of Science and Engineering, Yongzhou 425100, China;1. Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China;2. China Crop Protection Industry Association, Beijing 100723, China
Abstract:The recent molecular iodine catalyzed [1,2]-rearrangement of aryl amines and 3-amino-1H-indazolesfor the synthesis of 1,2,3-benzotriazines is highlighted.
Keywords:Iodine  Metal-free  Rearrangement reaction  1,2,3-Benzotriazines
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